Trimethylsulfonium iodide - CAS 2181-42-2
Catalog: |
BB017155 |
Product Name: |
Trimethylsulfonium iodide |
CAS: |
2181-42-2 |
Synonyms: |
Sulfonium, trimethyl-, iodide (1:1); Sulfonium, trimethyl-, iodide; Trimethyl-λ[3]-sulfane hydroiodide; Trimethylsulphonium iodide |
Related CAS: | 1232233-67-8 (Deleted CAS) 676-84-6 (free base)
|
IUPAC Name: | trimethylsulfanium;iodide |
Description: | Treatment with strong base yields the dimethylsulfonium methylide which reacts in-situ with the carbonyl group of ketones to form epoxides or allylic alcohols. |
Molecular Weight: | 204.07 |
Molecular Formula: | C3H9IS |
Canonical SMILES: | C[S+](C)C.[I-] |
InChI: | InChI=1S/C3H9S.HI/c1-4(2)3;/h1-3H3;1H/q+1;/p-1 |
InChI Key: | VFJYIHQDILEQNR-UHFFFAOYSA-M |
Melting Point: | 203-207°C |
Purity: | ≥95% |
Solubility: | Soluble in Methanol |
Appearance: | White to light yellow powder, crystalline powder and/or chunks |
Storage: | Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. |
MDL: | MFCD00011632 |
LogP: | -2.50190 |
GHS Hazard Statement: | H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation] |
Precautionary Statement: | P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501 |
Signal Word: | Warning |
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PMID | Publication Date | Title | Journal |
19559444 | 20090731 | Use of an injection port for thermochemolysis-gas chromatography/mass spectrometry: rapid profiling of biomaterials | Journal of chromatography. A |
19223033 | 20090410 | Reaction efficiency of organic alkalis with various classes of lipids during thermally assisted hydrolysis and methylation | Journal of chromatography. A |
18385839 | 20080421 | Urea derivatives are highly active catalysts for the base-mediated generation of terminal epoxides from aldehydes and trimethylsulfonium iodide | Organic & biomolecular chemistry |
16782113 | 20060901 | Study of different parameters affecting the derivatization of acidic herbicides with trimethylsulfonium hydroxide to make them suitable for gas chromatography analysis | Journal of chromatography. A |
15481466 | 20040820 | Trimethylsulfonium hydroxide as derivatization reagent for the chemical investigation of drying oils in works of art by gas chromatography | Journal of chromatography. A |
Complexity: | 8 |
Compound Is Canonicalized: | Yes |
Covalently-Bonded Unit Count: | 2 |
Defined Atom Stereocenter Count: | 0 |
Defined Bond Stereocenter Count: | 0 |
Exact Mass: | 203.94697 |
Formal Charge: | 0 |
Heavy Atom Count: | 5 |
Hydrogen Bond Acceptor Count: | 1 |
Hydrogen Bond Donor Count: | 0 |
Isotope Atom Count: | 0 |
Monoisotopic Mass: | 203.94697 |
Rotatable Bond Count: | 0 |
Topological Polar Surface Area: | 1 Å2 |
Undefined Atom Stereocenter Count: | 0 |
Undefined Bond Stereocenter Count: | 0 |
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