Lithium 2,2,6,6-tetramethylpiperidide - CAS 38227-87-1

Catalog:	BB023588
Product Name:	Lithium 2,2,6,6-tetramethylpiperidide
CAS:	38227-87-1
Synonyms:	lithium;2,2,6,6-tetramethylpiperidin-1-ide; lithium;2,2,6,6-tetramethylpiperidin-1-ide

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Computed Properties

IUPAC Name:	lithium;2,2,6,6-tetramethylpiperidin-1-ide
Description:	Lithium 2,2,6,6-tetramethylpiperidide (CAS# 38227-87-1 ) is a useful research chemical.
Molecular Weight:	147.19
Molecular Formula:	C9H18NLi
Canonical SMILES:	[Li+].CC1(CCCC([N-]1)(C)C)C
InChI:	InChI=1S/C9H18N.Li/c1-8(2)6-5-7-9(3,4)10-8;/h5-7H2,1-4H3;/q-1;+1
InChI Key:	ANYSGBYRTLOUPO-UHFFFAOYSA-N
LogP:	2.43170

Publication Number	Title	Priority Date
CN-113292479-A	Preparation method of 5-azaspiro [2.4] heptane and salt thereof	20210527
CN-112830933-A	Synthetic method of 3, 4-dihydro-2H-pyrano [2,3-b ] pyridine	20210204
CN-112574247-A	Synthesis method for synthesizing 4-ethynyl-tetrahydropyran from 2,2' -dichloroethyl ether	20201225
WO-2021204855-A1	Microbiocidal quinoline dihydropyrrolopyrazine derivatives	20200408
WO-2021198283-A1	Inhibitors of antigen presentation by hla-dr	20200331

PMID	Publication Date	Title	Journal
22897831	20120907	syn-β-Hydroxyallylic silanes from terminal epoxide α-lithiation-silylation and alkenylation: application to the tetrahydrofuran portion of the lytophilippines	Organic letters
22159308	20120214	After-effects of lithium-mediated alumination of 3-iodoanisole: isolation of molecular salt elimination and trapped-benzyne products	Dalton transactions (Cambridge, England : 2003)
21629913	20110721	Rearrangement of lithiated S-alkyl O,O-dialkyl thiophosphates: scope and stereochemistry of the thiophosphate-mercaptophosphonate rearrangement	Organic & biomolecular chemistry
21977207	20110101	Selectivity in C-alkylation of dianions of protected 6-methyluridine	Beilstein journal of organic chemistry
20063852	20100402	Stereocontrolled syntheses of (-)-cubebol and (-)-10-epicubebol involving intramolecular cyclopropanation of alpha-lithiated epoxides	The Journal of organic chemistry

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Related Functional Groups

Piperidines

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[681428-42-2]
Ethyl 1-(1-methylpyrazolo[3,4-d]pyrimidin-4-yl)piperidine-4-carboxylate
[1189664-19-4]
Ethyl 1-(3-chlorobenzyl)piperidine-3-carboxylate hydrochloride
[217487-18-8]
Ethyl 1-(methylsulfonyl)piperidine-4-carboxylate
[1172760-90-5]
Ethyl 1-[(1,3,5-trimethyl-1H-pyrazol-4-yl)methyl]piperidine-3-carboxylate
[1006334-33-3]
Ethyl 1-[(1-ethyl-1H-pyrazol-4-yl)methyl]piperidine-4-carboxylate

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GHS Hazard Statement:	H261 (100%): In contact with water releases flammable gas [Danger Substances and mixtures which in contact with water, emit flammable gases]; H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]
Precautionary Statement:	P231+P232, P260, P264, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P402+P404, P405, and P501
Signal Word:	Danger

Complexity:	116
Compound Is Canonicalized:	Yes
Covalently-Bonded Unit Count:	2
Defined Atom Stereocenter Count:	0
Defined Bond Stereocenter Count:	0
Exact Mass:	147.15992801
Formal Charge:	0
Heavy Atom Count:	11
Hydrogen Bond Acceptor Count:	1
Hydrogen Bond Donor Count:	0
Isotope Atom Count:	0
Monoisotopic Mass:	147.15992801
Rotatable Bond Count:	0
Topological Polar Surface Area:	1
Undefined Atom Stereocenter Count:	0
Undefined Bond Stereocenter Count:	0