Triphenyl Borate - CAS 1095-03-0
Catalog: |
BB002503 |
Product Name: |
Triphenyl Borate |
CAS: |
1095-03-0 |
Synonyms: |
triphenyl borate; triphenyl borate |
IUPAC Name: | triphenyl borate |
Description: | Catalyst involved in: Multicomponent aziridination of aldehydes; Hetero-Diels-Alder reactions and Mukaiyama aldol condensation; Cross-metathesis of alkenes with 3-nitropropene; Asymmetric Claisen rearrangement of unactivated allyl vinyl ethers; Ethoxylation; Asymmetric aziridination of imines. |
Molecular Weight: | 290.12 |
Molecular Formula: | C18H15O3B |
Canonical SMILES: | B(OC1=CC=CC=C1)(OC2=CC=CC=C2)OC3=CC=CC=C3 |
InChI: | InChI=1S/C18H15BO3/c1-4-10-16(11-5-1)20-19(21-17-12-6-2-7-13-17)22-18-14-8-3-9-15-18/h1-15H |
InChI Key: | MDCWDBMBZLORER-UHFFFAOYSA-N |
Boiling Point: | 343.2 °C at 760 mmHg |
Melting Point: | 98-101 °C (lit.) |
Flash Point: | Not applicable |
Purity: | ≥ 97 % |
Density: | 1.134 g/cm3 |
Appearance: | Solid |
Storage: | Inert atmosphere, 2-8 °C |
MDL: | MFCD00059011 |
LogP: | 4.20830 |
GHS Hazard Statement: | H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral] |
Precautionary Statement: | P261, P264, P270, P271, P280, P301+P310, P302+P352, P304+P340, P305+P351+P338, P310, P311, P312, P321, P322, P330, P361, P363, P403+P233, P405, and P501 |
Signal Word: | Danger |
Publication Number | Title | Priority Date |
WO-2015192231-A1 | Lithographic printing plates precursors comprising a radiation sensitive imageable layer with a crosslinked surface | 20140620 |
WO-2015102979-A1 | Curable organosiloxane oligomer compositions | 20131231 |
US-2015037690-A1 | Electrolytes for stable cycling of high capacity lithium based batteries | 20130802 |
EP-2826826-A1 | Composition for forming a coating type BPSG film, substrate formed a film by said composition, and patterning process using said composition | 20130627 |
US-2015004791-A1 | Composition for forming a coating type bpsg film, substrate formed a film by said composition, and patterning process using said composition | 20130627 |
PMID | Publication Date | Title | Journal |
22253063 | 20120301 | First isolation of disubstituted cis-5,6-dihydro-1,10-phenanthrolines. Lipase-mediated resolution of cis- and trans-phenoxy alcohol isomers and assignment of absolute stereochemistry via CD and NMR spectroscopy | Chirality |
19921061 | 20091214 | Synthesis and characterization of neutral iron(II) and ruthenium(II) complexes with the isocyanotriphenylborate ligand | Dalton transactions (Cambridge, England : 2003) |
18306265 | 20080101 | Catalytic asymmetric aziridination with borate catalysts derived from VANOL and VAPOL ligands: scope and mechanistic studies | Chemistry (Weinheim an der Bergstrasse, Germany) |
17673572 | 20071101 | Pharmacological characterization and molecular determinants of the activation of transient receptor potential V2 channel orthologs by 2-aminoethoxydiphenyl borate | Molecular pharmacology |
17497860 | 20070606 | Direct access to N-H-aziridines from asymmetric catalytic aziridination with borate catalysts derived from vaulted binaphthol and vaulted biphenanthrol ligands | Journal of the American Chemical Society |
Complexity: | 247 |
Compound Is Canonicalized: | Yes |
Covalently-Bonded Unit Count: | 1 |
Defined Atom Stereocenter Count: | 0 |
Defined Bond Stereocenter Count: | 0 |
Exact Mass: | 290.1114245 |
Formal Charge: | 0 |
Heavy Atom Count: | 22 |
Hydrogen Bond Acceptor Count: | 3 |
Hydrogen Bond Donor Count: | 0 |
Isotope Atom Count: | 0 |
Monoisotopic Mass: | 290.1114245 |
Rotatable Bond Count: | 6 |
Topological Polar Surface Area: | 27.7 Å2 |
Undefined Atom Stereocenter Count: | 0 |
Undefined Bond Stereocenter Count: | 0 |
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