Trimethyl(trifluoromethyl)silane - CAS 81290-20-2

Catalog:	BB036641
Product Name:	Trimethyl(trifluoromethyl)silane
CAS:	81290-20-2
Synonyms:	trimethyl(trifluoromethyl)silane

Technical Data

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Computed Properties

IUPAC Name:	trimethyl(trifluoromethyl)silane
Description:	Trimethyl(trifluoromethyl)silane (CAS# 81290-20-2) is a reagent used in the trifluoromethylation of alkyl compounds.
Molecular Weight:	142.19
Molecular Formula:	C4H9F3Si
Canonical SMILES:	C[Si](C)(C)C(F)(F)F
InChI:	InChI=1S/C4H9F3Si/c1-8(2,3)4(5,6)7/h1-3H3
InChI Key:	MWKJTNBSKNUMFN-UHFFFAOYSA-N
Boiling Point:	49 °C
Purity:	98 %
Density:	0.969 g/cm³
Appearance:	Clear colorless solution
Storage:	2-8 °C
MDL:	MFCD00145454
LogP:	2.84600

Publication Number	Title	Priority Date
US-2016257633-A1	Processes for preparing (r)-1-(5-chloro-[1,1`-biphenyl]-2-yl)-2,2,2-trifluoroethanol and 1-(5-chloro-[1,1`-biphenyl]-2-yl)-2,2,2-trifluoroethanone	20150305
US-2016264567-A1	Substituted sulfonamide compounds	20150215
US-2016229843-A1	Aza-heteroaryl compounds as pi3k-gamma inhibitors	20150209
US-2016185785-A1	Pyrrolo and pyrazolopyrimidines as ubiquitin-specific protease 7 inhibitors	20141230
US-2016176864-A1	Novel tricyclic compounds as anticancer agents	20141223

PMID	Publication Date	Title	Journal
22965685	20121015	Copper-catalyzed nucleophilic trifluoromethylation of allylic halides: a simple approach to allylic trifluoromethylation	Chemistry (Weinheim an der Bergstrasse, Germany)
22497319	20120420	Copper-catalyzed oxidative trifluoromethylation of terminal alkenes using nucleophilic CF3SiMe3: efficient C(sp3)-CF3 bond formation	Organic letters
22334380	20120319	Stereoselective access to fluorinated and non-fluorinated quaternary piperidines: synthesis of pipecolic acid and iminosugar derivatives	Chemistry (Weinheim an der Bergstrasse, Germany)
22287539	20120305	Copper-catalyzed oxidative trifluoromethylthiolation of aryl boronic acids with TMSCF3 and elemental sulfur	Angewandte Chemie (International ed. in English)
22251059	20120203	Copper-catalyzed oxidative trifluoromethylation of terminal alkynes and aryl boronic acids using (trifluoromethyl)trimethylsilane	The Journal of organic chemistry

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GHS Hazard Statement:	H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]
Precautionary Statement:	P210, P233, P240, P241, P242, P243, P261, P264, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P370+P378, P403+P233, P403+P235, P405, and P501
Signal Word:	Danger

Complexity:	78.3
Compound Is Canonicalized:	Yes
Covalently-Bonded Unit Count:	1
Defined Atom Stereocenter Count:	0
Defined Bond Stereocenter Count:	0
Exact Mass:	142.04256131
Formal Charge:	0
Heavy Atom Count:	8
Hydrogen Bond Acceptor Count:	3
Hydrogen Bond Donor Count:	0
Isotope Atom Count:	0
Monoisotopic Mass:	142.04256131
Rotatable Bond Count:	0
Topological Polar Surface Area:	0 Å²
Undefined Atom Stereocenter Count:	0
Undefined Bond Stereocenter Count:	0