Trifluoromethanesulfonimide - CAS 82113-65-3
Catalog: |
BB036757 |
Product Name: |
Trifluoromethanesulfonimide |
CAS: |
82113-65-3 |
Synonyms: |
1,1,1-trifluoro-N-(trifluoromethylsulfonyl)methanesulfonamide |
IUPAC Name: | 1,1,1-trifluoro-N-(trifluoromethylsulfonyl)methanesulfonamide |
Description: | Trifluoromethanesulfonimide (CAS# 82113-65-3) is commonly used as a strong acid to prepare Lewis Acid catalysts. It can also be used to improve efficiency of graphene/silicon Schottky solar cells by chemical doping and as a solvent for recycling battery electrodes. |
Molecular Weight: | 281.15 |
Molecular Formula: | C2HF6NO4S2 |
Canonical SMILES: | C(F)(F)(F)S(=O)(=O)NS(=O)(=O)C(F)(F)F |
InChI: | InChI=1S/C2HF6NO4S2/c3-1(4,5)14(10,11)9-15(12,13)2(6,7)8/h9H |
InChI Key: | ZXMGHDIOOHOAAE-UHFFFAOYSA-N |
Boiling Point: | 190.5 °C at 760 mmHg |
Melting Point: | 52-56 °C |
Purity: | 95 % |
Density: | 1.936 g/cm3 |
Appearance: | Light yellow to brown liquid |
Storage: | 2-8 °C |
MDL: | MFCD00214154 |
LogP: | 2.82770 |
GHS Hazard Statement: | H301 (50%): Toxic if swallowed [Danger Acute toxicity, oral] |
Precautionary Statement: | P260, P264, P270, P280, P301+P310, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P330, P363, P405, and P501 |
Signal Word: | Danger |
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PMID | Publication Date | Title | Journal |
23044100 | 20130102 | Characterization of conducting cellulose acetate based polymer electrolytes doped with 'green' ionic mixture | Carbohydrate polymers |
23023783 | 20121121 | Rhodium complexes stabilized by phosphine-functionalized phosphonium ionic liquids used as higher alkene hydroformylation catalysts: influence of the phosphonium headgroup on catalytic activity | Dalton transactions (Cambridge, England : 2003) |
23013036 | 20121025 | Rotational diffusion of nonpolar and ionic solutes in 1-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imides: is solute rotation always influenced by the length of the alkyl chain on the imidazolium cation? | The journal of physical chemistry. B |
23030499 | 20121019 | Trimethylaluminum-triflimide complexes for the catalysis of highly hindered Diels-Alder reactions | Organic letters |
22975189 | 20121009 | Ionic liquids as porogens in the microwave-assisted synthesis of methacrylate monoliths for chromatographic application | Analytica chimica acta |
Complexity: | 374 |
Compound Is Canonicalized: | Yes |
Covalently-Bonded Unit Count: | 1 |
Defined Atom Stereocenter Count: | 0 |
Defined Bond Stereocenter Count: | 0 |
Exact Mass: | 280.92511883 |
Formal Charge: | 0 |
Heavy Atom Count: | 15 |
Hydrogen Bond Acceptor Count: | 11 |
Hydrogen Bond Donor Count: | 1 |
Isotope Atom Count: | 0 |
Monoisotopic Mass: | 280.92511883 |
Rotatable Bond Count: | 2 |
Topological Polar Surface Area: | 97.1 Å2 |
Undefined Atom Stereocenter Count: | 0 |
Undefined Bond Stereocenter Count: | 0 |
XLogP3: | 1.3 |
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