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| IUPAC Name: | chlororuthenium(1+)[(1S,2S)-2-[2-[(4-methylphenyl)methoxy]ethylamino]-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide |
| Description: | (S,S)-Ts-DENEB (regR) (CAS# 1384974-37-1) is a catalyst used in transfer hydrogenation reactions, such as in the selective asymmetric transfer hydrogenation of α-substituted acetophenones, and asymmetric transfer hydrogenation of aryl N-heteroaryl ketones. |
| Molecular Weight: | 650.19 |
| Molecular Formula: | C31H33ClN2O3RuS |
| Canonical SMILES: | CC1=CC=C(C=C1)COCCNC(C2=CC=CC=C2)C(C3=CC=CC=C3)[N-]S(=O)(=O)C4=CC=C(C=C4)C.Cl[Ru+] |
| InChI: | InChI=1S/C31H33N2O3S.ClH.Ru/c1-24-13-17-26(18-14-24)23-36-22-21-32-30(27-9-5-3-6-10-27)31(28-11-7-4-8-12-28)33-37(34,35)29-19-15-25(2)16-20-29/h3-20,30-32H,21-23H2,1-2H31H/q-1+2/p-1/t30-,31-/m0../s1 |
| InChI Key: | INKUCOHLIHBSDN-YBZGWEFGSA-M |
| References: | Wang, B.; et al. Organic Letters, 19, 2094 (2017); Yuki, Y.; et al. Advanced Synthesis and Catalysis, 360, 568 (2018). |
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