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| IUPAC Name: | [1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphanedichlororutheniumpyridin-2-ylmethanamine |
| Description: | (R)-Tol-Binap RuCl2 AMPY is a chiral ruthenium complex with catalyst use to enantioselectively hydrogenate various simple ketones. |
| Molecular Weight: | 958.9 |
| Molecular Formula: | C54H48Cl2N2P2Ru |
| Canonical SMILES: | CC1=CC=C(C=C1)P(C2=CC=C(C=C2)C)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=C(C=C7)C)C8=CC=C(C=C8)C.C1=CC=NC(=C1)CN.Cl[Ru]Cl |
| InChI: | InChI=1S/C48H40P2.C6H8N2.2ClH.Ru/c1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-427-5-6-3-1-2-4-8-6/h5-32H,1-4H31-4H,5,7H22*1H/q+2/p-2 |
| InChI Key: | UCHLDFFOSWUXLN-UHFFFAOYSA-L |
| References: | Ohkuma, Takeshi., Journal of the American Chemical Society, 127, 8288-8289, (2005). |
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