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(R)-Tol-Binap RuCl2 AMPY

(R)-Tol-Binap RuCl2 AMPY - CAS 858116-31-1

Catalog:	BB057393
Product Name:	(R)-Tol-Binap RuCl2 AMPY
CAS:	858116-31-1
Synonyms:	Dichloro[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](2-aminomethylpyridine)ruthenium(II)

(R)-Tol-Binap RuCl2 AMPY

Technical Data

Safety and Hazards

Computed Properties

IUPAC Name:	[1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphanedichlororutheniumpyridin-2-ylmethanamine
Description:	(R)-Tol-Binap RuCl2 AMPY is a chiral ruthenium complex with catalyst use to enantioselectively hydrogenate various simple ketones.
Molecular Weight:	958.9
Molecular Formula:	C54H48Cl2N2P2Ru
Canonical SMILES:	CC1=CC=C(C=C1)P(C2=CC=C(C=C2)C)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=C(C=C7)C)C8=CC=C(C=C8)C.C1=CC=NC(=C1)CN.Cl[Ru]Cl
InChI:	InChI=1S/C48H40P2.C6H8N2.2ClH.Ru/c1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-427-5-6-3-1-2-4-8-6/h5-32H,1-4H31-4H,5,7H22*1H/q+2/p-2
InChI Key:	UCHLDFFOSWUXLN-UHFFFAOYSA-L
References:	Ohkuma, Takeshi., Journal of the American Chemical Society, 127, 8288-8289, (2005).

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