IUPAC Name: | chlororuthenium(1+)[(1R,2R)-2-[2-[(4-methylphenyl)methoxy]ethylamino]-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide |
Description: | (R,R)-Ts-DENEB (CAS# 1333981-84-2) is a catalyst used in asymmetric hydrogen transfer reactions, such as in the synthesis of 2-(1,2,3,4-tetrahydro-1-isoquinolyl)ethanol derivatives. (R,R)-Ts-DENEB is used to form hydrogen carrier systems, where the catalytic dehydrogenative coupling of methanol and 1,2-diamine is used to generate H2 without the production of CO2. |
Molecular Weight: | 650.19 |
Molecular Formula: | C31H33ClN2O3RuS |
Canonical SMILES: | CC1=CC=C(C=C1)COCCNC(C2=CC=CC=C2)C(C3=CC=CC=C3)[N-]S(=O)(=O)C4=CC=C(C=C4)C.Cl[Ru+] |
InChI: | InChI=1S/C31H33N2O3S.ClH.Ru/c1-24-13-17-26(18-14-24)23-36-22-21-32-30(27-9-5-3-6-10-27)31(28-11-7-4-8-12-28)33-37(34,35)29-19-15-25(2)16-20-29/h3-20,30-32H,21-23H2,1-2H31H/q-1+2/p-1/t30-,31-/m1../s1 |
InChI Key: | INKUCOHLIHBSDN-ZAMYOOMVSA-M |
References: | Zheng, L.; et al. Organic Chemistry Frontiers, 5, 1366 (2018); Kothandaraman, J., et al. J. Am. Chem. Soc., 139, 2549 (2017).. |
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