(R,R)-Ts-DENEB - CAS 1333981-84-2

Catalog:	BB057008
Product Name:	(R,R)-Ts-DENEB
CAS:	1333981-84-2
Synonyms:	chloro[4-methyl-N-[(1R,2R)-2-[(S)-[2-[[(1,2,3,4,5,6-η)-4-methylphenyl]methoxy]ethyl]amino-κN]-1,2-diphenylethyl]benzenesulfonamidato-κN]-Ruthenium stereoisomer; stereoisomer of Chloro[4-methyl-N-[(1R,2R)-2-[(S)-[2-[[(1,2,3,4,5,6-η)-4-methylphenyl]methoxy]ethyl]amino-κN]-1,2-diphenylethyl]benzenesulfonamidato-κN]ruthenium; (R,R)-Ts-DENEB

(R,R)-Ts-DENEB

Technical Data

Safety and Hazards

Computed Properties

IUPAC Name:	chlororuthenium(1+)[(1R,2R)-2-[2-[(4-methylphenyl)methoxy]ethylamino]-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide
Description:	(R,R)-Ts-DENEB (CAS# 1333981-84-2) is a catalyst used in asymmetric hydrogen transfer reactions, such as in the synthesis of 2-(1,2,3,4-tetrahydro-1-isoquinolyl)ethanol derivatives. (R,R)-Ts-DENEB is used to form hydrogen carrier systems, where the catalytic dehydrogenative coupling of methanol and 1,2-diamine is used to generate H2 without the production of CO2.
Molecular Weight:	650.19
Molecular Formula:	C31H33ClN2O3RuS
Canonical SMILES:	CC1=CC=C(C=C1)COCCNC(C2=CC=CC=C2)C(C3=CC=CC=C3)[N-]S(=O)(=O)C4=CC=C(C=C4)C.Cl[Ru+]
InChI:	InChI=1S/C31H33N2O3S.ClH.Ru/c1-24-13-17-26(18-14-24)23-36-22-21-32-30(27-9-5-3-6-10-27)31(28-11-7-4-8-12-28)33-37(34,35)29-19-15-25(2)16-20-29/h3-20,30-32H,21-23H2,1-2H31H/q-1+2/p-1/t30-,31-/m1../s1
InChI Key:	INKUCOHLIHBSDN-ZAMYOOMVSA-M
References:	Zheng, L.; et al. Organic Chemistry Frontiers, 5, 1366 (2018); Kothandaraman, J., et al. J. Am. Chem. Soc., 139, 2549 (2017)..

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