(R)-2,2'-Diamino-1,1'-binaphthalene - CAS 18741-85-0
Catalog: |
BB014426 |
Product Name: |
(R)-2,2'-Diamino-1,1'-binaphthalene |
CAS: |
18741-85-0 |
Synonyms: |
1-(2-amino-1-naphthalenyl)-2-naphthalenamine; 1-(2-aminonaphthalen-1-yl)naphthalen-2-amine |
Application: |
(R)-(+)-1,1'-Bi(2-naphthylamine) is a chiral auxiliary |
IUPAC Name: | 1-(2-aminonaphthalen-1-yl)naphthalen-2-amine |
Description: | (R)-2,2'-Diamino-1,1'-binaphthalene (CAS# 18741-85-0) is a chiral auxiliary. |
Molecular Weight: | 284.35 |
Molecular Formula: | C20H16N2 |
Canonical SMILES: | C1=CC=C2C(=C1)C=CC(=C2C3=C(C=CC4=CC=CC=C43)N)N |
InChI: | InChI=1S/C20H16N2/c21-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)22/h1-12H,21-22H2 |
InChI Key: | DDAPSNKEOHDLKB-UHFFFAOYSA-N |
Boiling Point: | 480.8 °C / 760 mmHg |
Melting Point: | 242 °C |
Purity: | 99 % |
Density: | 1.25 g/cm3 |
Solubility: | Slightly soluble in water. |
Appearance: | Powder or crystals |
Storage: | Room temperature. |
MDL: | MFCD00145204 |
LogP: | 5.98680 |
GHS Hazard Statement: | H302 (90.48%): Harmful if swallowed [Warning Acute toxicity, oral] |
Precautionary Statement: | P264, P270, P280, P301+P312, P305+P351+P338, P310, P330, and P501 |
Signal Word: | Danger |
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PMID | Publication Date | Title | Journal |
22865751 | 20120801 | A novel chiral mesoporous binaphthyl-silicas: preparation, characterization, and application in HPLC | Journal of separation science |
22514086 | 20120528 | Enantioselective direct aldol reaction of α-keto esters catalyzed by (S(a))-binam-D-prolinamide under quasi solvent-free conditions | Organic & biomolecular chemistry |
22407327 | 20120428 | Mono- and dinuclear nickel(II) complexes of resolved Schiff-base ligands with extended quinoline substituents | Dalton transactions (Cambridge, England : 2003) |
22329623 | 20120315 | Structural identification of a novel axially chiral binaphthyl fluorene based salen ligand in solution using electronic circular dichroism: a theoretical-experimental analysis | The journal of physical chemistry. A |
22199617 | 20111201 | [2,2'-(1,1'-Binaphthyl-2,2'-diyldiimino)-diethanol-κN,N',O]dichloridocopper(II) | Acta crystallographica. Section E, Structure reports online |
Complexity: | 346 |
Compound Is Canonicalized: | Yes |
Covalently-Bonded Unit Count: | 1 |
Defined Atom Stereocenter Count: | 0 |
Defined Bond Stereocenter Count: | 0 |
Exact Mass: | 284.131348519 |
Formal Charge: | 0 |
Heavy Atom Count: | 22 |
Hydrogen Bond Acceptor Count: | 2 |
Hydrogen Bond Donor Count: | 2 |
Isotope Atom Count: | 0 |
Monoisotopic Mass: | 284.131348519 |
Rotatable Bond Count: | 1 |
Topological Polar Surface Area: | 52 Å2 |
Undefined Atom Stereocenter Count: | 0 |
Undefined Bond Stereocenter Count: | 0 |
XLogP3: | 4.7 |
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