Potassium (Z)-2-Buten-2-yltrifluoroborate - CAS 1134643-88-1
Catalog: |
BB003185 |
Product Name: |
Potassium (Z)-2-Buten-2-yltrifluoroborate |
CAS: |
1134643-88-1 |
Synonyms: |
potassium;[(Z)-but-2-en-2-yl]-trifluoroboranuide; potassium;[(Z)-but-2-en-2-yl]-trifluoroboranuide |
IUPAC Name: | potassium;[(Z)-but-2-en-2-yl]-trifluoroboranuide |
Description: | Potassium (2Z)-2-buten-2-yltrifluoroborate can be used as a substrate: In the asymmetric alkenylation of imines/aldimines using a rhodium based catalyst; In the Rh(I)-catalyzed allylic amines synthesis by reacting with N-tert-butanesulfinyl aldimines; In the ytterbium triflate catalyzed multicomponent synthesis of β-unsaturated α-amino esters. |
Molecular Weight: | 162.00 |
Molecular Formula: | C4H7F3BK |
Canonical SMILES: | [B-](C(=CC)C)(F)(F)F.[K+] |
InChI: | InChI=1S/C4H7BF3.K/c1-3-4(2)5(6,7)8;/h3H,1-2H3;/q-1;+1/b4-3+; |
InChI Key: | IFJZXYDBLMMRCO-BJILWQEISA-N |
Melting Point: | 147-152 °C |
Flash Point: | Not applicable |
Purity: | ≥ 95 % |
Solubility: | Water : Soluble |
Appearance: | Solid |
Storage: | 2-8 °C |
LogP: | 2.33920 |
GHS Hazard Statement: | H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]; H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]; H335 (100%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation] |
Precautionary Statement: | P302 + P352 - P305 + P351 + P338 |
Signal Word: | Warning |
Publication Number | Title | Priority Date |
WO-2021130638-A1 | Diacylglycerol kinase modulating compounds | 20191224 |
WO-2019213006-A1 | Substituted pyrimidinones as agonists of the apj receptor | 20180501 |
EP-3788037-A1 | Substituted pyrimidinones as agonists of the apj receptor | 20180501 |
US-2021246118-A1 | Substituted pyrimidinones as agonists of the apj receptor | 20180501 |
WO-2019089335-A1 | Fused triazole agonists of the apj receptor | 20171103 |
Complexity: | 107 |
Compound Is Canonicalized: | Yes |
Covalently-Bonded Unit Count: | 2 |
Defined Atom Stereocenter Count: | 0 |
Defined Bond Stereocenter Count: | 1 |
Exact Mass: | 162.0229964 |
Formal Charge: | 0 |
Heavy Atom Count: | 9 |
Hydrogen Bond Acceptor Count: | 4 |
Hydrogen Bond Donor Count: | 0 |
Isotope Atom Count: | 0 |
Monoisotopic Mass: | 162.0229964 |
Rotatable Bond Count: | 0 |
Topological Polar Surface Area: | 0 |
Undefined Atom Stereocenter Count: | 0 |
Undefined Bond Stereocenter Count: | 0 |
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