D-Prolinol - CAS 68832-13-3

Catalog:	BB033638
Product Name:	D-Prolinol
CAS:	68832-13-3
Synonyms:	(R)-2-Hydroxymethyl-pyrrolidine; (R)-2-Pyrrolidinemethanol; (R)-(−)-2-Pyrrolidinemethanol

Technical Data

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Computed Properties

IUPAC Name:	[(2R)-pyrrolidin-2-yl]methanol
Description:	A reagent used for asymmetric synthesis.
Molecular Weight:	101.2
Molecular Formula:	C5H11NO
Canonical SMILES:	C1CC(NC1)CO
InChI:	InChI=1S/C5H11NO/c7-4-5-2-1-3-6-5/h5-7H,1-4H2/t5-/m1/s1
InChI Key:	HVVNJUAVDAZWCB-RXMQYKEDSA-N
Boiling Point:	74-76 °C at 2 mmHg
Purity:	> 95 % by HPLC
Density:	1.025 g/mL
Appearance:	Colorless transparent or pale yellow liquid
Storage:	Store at 2-8 °C
MDL:	MFCD00064321
LogP:	0.05950

Publication Number	Title	Priority Date
CN-112979532-A	Phthalimide compound, preparation method and application	20210520
CN-112979532-B	Phthalimide compound, preparation method and application	20210520
CN-112812101-A	Preparation method of avanafil impurity	20210119
CN-112430237-A	Desulfurizing agent containing phthalocyanine double activity, preparation method and application thereof	20201211
CN-111484484-A	2, 4-diaryl aminopyrimidine derivative containing aromatic heterocycle and preparation and application thereof	20200413

PMID	Publication Date	Title	Journal
22585353	20120814	Efficient proline and prolinol ether mediated 3-component synthesis of 3- and 3,4-substituted chromenone derivatives	Organic & biomolecular chemistry
22434659	20120416	Asymmetric Michael addition of N-boc-protected oxindoles to nitroalkenes catalyzed by a chiral secondary amine	Chemistry (Weinheim an der Bergstrasse, Germany)
22374840	20120319	Unifying metal- and organocatalysis for asymmetric oxidative iminium activation: a relay catalytic system enabling the combined allylic oxidation of alcohols and prolinol ether catalyzed iminium reactions	Chemistry (Weinheim an der Bergstrasse, Germany)
22224938	20120120	Relative tendency of carbonyl compounds to form enamines	Organic letters
21552582	20110621	Asymmetric alkynylation of aldehydes with propiolates without high reagent loading and any additives	Organic & biomolecular chemistry

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GHS Hazard Statement:	H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]
Precautionary Statement:	P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501
Signal Word:	Warning

Complexity:	56
Compound Is Canonicalized:	Yes
Covalently-Bonded Unit Count:	1
Defined Atom Stereocenter Count:	1
Defined Bond Stereocenter Count:	0
Exact Mass:	101.084063974
Formal Charge:	0
Heavy Atom Count:	7
Hydrogen Bond Acceptor Count:	2
Hydrogen Bond Donor Count:	2
Isotope Atom Count:	0
Monoisotopic Mass:	101.084063974
Rotatable Bond Count:	1
Topological Polar Surface Area:	32.3 Å²
Undefined Atom Stereocenter Count:	0
Undefined Bond Stereocenter Count:	0
XLogP3:	-0.3