Bis(2-diphenylphosphinophenyl)ether - CAS 166330-10-5
Catalog: |
BB012270 |
Product Name: |
Bis(2-diphenylphosphinophenyl)ether |
CAS: |
166330-10-5 |
Synonyms: |
[2-(2-diphenylphosphinophenoxy)phenyl]-diphenylphosphine; [2-(2-diphenylphosphanylphenoxy)phenyl]-diphenylphosphane |
IUPAC Name: | [2-(2-diphenylphosphanylphenoxy)phenyl]-diphenylphosphane |
Description: | Bis(2-diphenylphosphinophenyl)ether (CAS# 166330-10-5) is shown to be used as a chelating ligand in a variety of inorganic reactions. One of which is the preparation of copper(I) dimethylbipyrimidine phosphinophenyl ether complexes. |
Molecular Weight: | 538.55 |
Molecular Formula: | C36H28OP2 |
Canonical SMILES: | C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3OC4=CC=CC=C4P(C5=CC=CC=C5)C6=CC=CC=C6 |
InChI: | InChI=1S/C36H28OP2/c1-5-17-29(18-6-1)38(30-19-7-2-8-20-30)35-27-15-13-25-33(35)37-34-26-14-16-28-36(34)39(31-21-9-3-10-22-31)32-23-11-4-12-24-32/h1-28H |
InChI Key: | RYXZOQOZERSHHQ-UHFFFAOYSA-N |
Boiling Point: | 608.19 °C at 760 mmHg |
MDL: | MFCD00233863 |
LogP: | 6.99530 |
GHS Hazard Statement: | H302 (92.08%): Harmful if swallowed [Warning Acute toxicity, oral] |
Precautionary Statement: | P264, P270, P273, P301+P312, P330, and P501 |
Signal Word: | Warning |
Publication Number | Title | Priority Date |
CN-113512427-A | Liquid crystal compound with negative dielectric anisotropy, liquid crystal composition and liquid crystal display device | 20210817 |
CN-113501793-A | Preparation method of stable isotope labeled nitrazepam internal standard reagent | 20210805 |
CN-113429391-A | Compound containing diphenyl sulfone skeleton and preparation method and application thereof | 20210714 |
CN-113480416-A | Preparation method of aryl ketone | 20210712 |
CN-113336937-A | Preparation method of polyamide 6 and polyamide 6 | 20210702 |
PMID | Publication Date | Title | Journal |
22772090 | 20120914 | Synthesis and characterisation of neutral mononuclear cuprous complexes based on dipyrrin derivatives and phosphine mixed-ligands | Dalton transactions (Cambridge, England : 2003) |
22580147 | 20120901 | Study on a phosphorescent copper(I) complex and its oxygen-sensing performances upon polystyrene and MCM-41 matrixes | Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy |
22238020 | 20120213 | Constrained digold(I) diaryls: syntheses, crystal structures, and photophysics | Chemistry (Weinheim an der Bergstrasse, Germany) |
22134379 | 20120128 | Neutral cuprous complexes as ratiometric oxygen gas sensors | Dalton transactions (Cambridge, England : 2003) |
22013883 | 20111118 | Palladium-catalyzed decarboxylative coupling of isatoic anhydrides with arylboronic acids | Organic letters |
Complexity: | 594 |
Compound Is Canonicalized: | Yes |
Covalently-Bonded Unit Count: | 1 |
Defined Atom Stereocenter Count: | 0 |
Defined Bond Stereocenter Count: | 0 |
Exact Mass: | 538.16153951 |
Formal Charge: | 0 |
Heavy Atom Count: | 39 |
Hydrogen Bond Acceptor Count: | 1 |
Hydrogen Bond Donor Count: | 0 |
Isotope Atom Count: | 0 |
Monoisotopic Mass: | 538.16153951 |
Rotatable Bond Count: | 8 |
Topological Polar Surface Area: | 9.2 Å2 |
Undefined Atom Stereocenter Count: | 0 |
Undefined Bond Stereocenter Count: | 0 |
XLogP3: | 8.8 |
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