Benzyl diazoacetate - CAS 52267-51-3
Catalog: |
BB027763 |
Product Name: |
Benzyl diazoacetate |
CAS: |
52267-51-3 |
Synonyms: |
benzyl 2-diazoacetate |
IUPAC Name: | benzyl 2-diazoacetate |
Description: | Benzyl diazoacetate (CAS# 52267-51-3 ) is a useful research chemical. |
Molecular Weight: | 176.17 |
Molecular Formula: | C9H8N2O2 |
Canonical SMILES: | C1=CC=C(C=C1)COC(=O)C=[N+]=[N-] |
InChI: | InChI=1S/C9H8N2O2/c10-11-6-9(12)13-7-8-4-2-1-3-5-8/h1-6H,7H2 |
InChI Key: | JBBKWIFIXPBQGZ-UHFFFAOYSA-N |
LogP: | 1.11146 |
GHS Hazard Statement: | H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]; H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]; H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]; H335 (100%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation] |
Precautionary Statement: | P261, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P319, P321, P330, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 |
Signal Word: | Warning |
Publication Number | Title | Priority Date |
US-11040939-B1 | N-transfer reagent and method for preparing the same and its application | 20200623 |
CN-111362795-A | Preparation method of substituted butyrate derivatives | 20200316 |
CN-111362795-B | Preparation method of substituted butyrate derivatives | 20200316 |
WO-2021039901-A1 | Method for producing peptide compound | 20190830 |
CN-110128341-A | A kind of chiral 2,2 '-bipyridine ligand and preparation method thereof and preparing the application in chiral cyclopropane derivative | 20190513 |
PMID | Publication Date | Title | Journal |
22458967 | 20120914 | Chromatographic examination of the chemical composition and sequence distribution of copolymers from ethyl and benzyl diazoacetate | Journal of chromatography. A |
15202890 | 20040625 | Stereoselective synthesis of 3-hydroxyproline benzyl esters from N-protected beta-aminoaldehydes and benzyl diazoacetate | The Journal of organic chemistry |
Complexity: | 216 |
Compound Is Canonicalized: | Yes |
Covalently-Bonded Unit Count: | 1 |
Defined Atom Stereocenter Count: | 0 |
Defined Bond Stereocenter Count: | 0 |
Exact Mass: | 176.058577502 |
Formal Charge: | 0 |
Heavy Atom Count: | 13 |
Hydrogen Bond Acceptor Count: | 3 |
Hydrogen Bond Donor Count: | 0 |
Isotope Atom Count: | 0 |
Monoisotopic Mass: | 176.058577502 |
Rotatable Bond Count: | 4 |
Topological Polar Surface Area: | 28.3 |
Undefined Atom Stereocenter Count: | 0 |
Undefined Bond Stereocenter Count: | 1 |
XLogP3: | 2.2 |
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