ruthenium(1+) hexafluorophosphate](https://resource.bocsci.com/structure/930601-66-4.gif)
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| Description: | (Acetonitrile)[4-tert-butyl-2-(diisopropylphosphino)-1-methyl-1H-imidazole-κN,κP](η5-cyclopentadienyl)ruthenium(1+) hexafluorophosphate, is an Alkene Zipper Catalyst, used in selective transformation of a large variety of ω-alkenyl cyclopropylcarbinols into stereodefined unconjugated (E)-acyclic aldehydes . |
| Molecular Weight: | 606.53 |
| Molecular Formula: | C21H35N3PRu⁺·PF6⁻ |
| Canonical SMILES: | CC#N.CC(C)P(C1=NC(=CN1C)C(C)(C)C)C(C)C.C1=C[CH]C=C1.F[P-](F)(F)(F)(F)F.[Ru+] |
| InChI: | InChI=1S/C14H27N2P.C5H5.C2H3N.F6P.Ru/c1-10(2)17(11(3)4)13-15-12(9-16(13)8)14(5,6)71-2-4-5-3-11-2-31-7(2,3,4,5)6/h9-11H,1-8H31-5H1H3/q-1+1 |
| InChI Key: | XHAIYVPZBQIYKW-UHFFFAOYSA-N |
| References: | Bruffaerts, J., Vasseur, A., & Marek, I. (2018). Alkene-Zipper Catalyzed Selective and Remote Retro-ene Reaction of Alkenyl Cyclopropylcarbinol. Advanced Synthesis & Catalysis, 360(7), 1389-1396.. |
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