![(Acetato-κO)[[2,2'-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-κN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-κO]](2-)]cobalt](https://resource.bocsci.com/structure/201870-82-8.gif)
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| IUPAC Name: | cobalt(3+)2,4-ditert-butyl-6-[[(1R,2R)-2-[(3,5-ditert-butyl-2-oxidophenyl)methylideneamino]cyclohexyl]iminomethyl]phenolateacetate |
| Description: | A cobalt complex used as a chiral selector of PVC membrane electrode. A highly active catalysts for the copolymerization of propylene oxide and carbon dioxide. (R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine (B431500) derivative, a ligand used in the preparation of Jacobsen's catalyst. |
| Molecular Weight: | 662.79 |
| Molecular Formula: | C38H55CoN2O4 |
| Canonical SMILES: | CC(=O)[O-].CC(C)(C)C1=CC(=C(C(=C1)C(C)(C)C)[O-])C=NC2CCCCC2N=CC3=C(C(=CC(=C3)C(C)(C)C)C(C)(C)C)[O-].[Co+3] |
| InChI: | InChI=1S/C36H54N2O2.C2H4O2.Co/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)121-2(3)4/h17-22,29-30,39-40H,13-16H2,1-12H31H3,(H,3,4)/q+3/p-3/t29-,30-/m1../s1 |
| InChI Key: | SZLTZRSRNDSBPH-SEILFYAJSA-K |
| Solubility: | Chloroform (Slightly), Dichloromethane (Slightly), Methanol (Very Slightly) |
| Appearance: | Brown to Black Solid |
| Storage: | 4°C |
| References: | Cohen, C. et al. J. Am. Chem. Soc., 127, 10869 (2005); Jacobsen, E.N. et al. J. Am. Chem. Soc., 113, 7063 (1991). |
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