9-Mesityl-10-methylacridinium Tetrafluoroborate - CAS 1442433-71-7

Catalog: BB056406
Product Name: 9-Mesityl-10-methylacridinium Tetrafluoroborate
CAS: 1442433-71-7
Synonyms: 10-Methyl-9-(2,4,6-trimethylphenyl)-acridinium Tetrafluoroborate(1-) (1:1)
9-Mesityl-10-methylacridinium Tetrafluoroborate
IUPAC Name:10-methyl-9-(2,4,6-trimethylphenyl)acridin-10-iumtetrafluoroborate
Description:9-Mesityl-10-methylacridinium Tetrafluoroborate can be used for the synthesis of γ-butyrolactones, γ-lactams and pyrrolidines. 9-Mesityl-10-methylacridinium Tetrafluoroborate has been reported by Nicewicz et al. to mediate myriad transformations through Photoredox Catalysis. The applications include the anti-Markovnikov hydroamination of alkenes and addition of carboxylic acids to alkenes and the hydrotrifluoromethylation of styrenes using the Langlois reagent S673690.
Molecular Weight:399.23
Molecular Formula:C23H22BF4N
Canonical SMILES:[B-](F)(F)(F)F.CC1=CC(=C(C(=C1)C)C2=C3C=CC=CC3=[N+](C4=CC=CC=C42)C)C
InChI:InChI=1S/C23H22N.BF4/c1-15-13-16(2)22(17(3)14-15)23-18-9-5-7-11-20(18)24(4)21-12-8-6-10-19(21)232-1(3,4)5/h5-14H,1-4H3/q+1-1
InChI Key:KKMWMXQQOIIJIZ-UHFFFAOYSA-N
Melting Point:>80°C (dec.)
Solubility:Chloroform (Slightly), Methanol (Slightly)
Appearance:Yellow to Dark Yellow Solid
Storage:Amber Vial, -20°C Freezer, Under inert atmosphere
References:Gesmundo, N. J. et al. Org. Lett. 17, 1316 (2015); Zeller, M. A., et al. Org. Lett. 16, 4810 (2014); Nicewicz et al., J. Am. Chem. Soc., 135 (26), 9588-9591(2013).

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