IUPAC Name: | 10-methyl-9-(2,4,6-trimethylphenyl)acridin-10-iumtetrafluoroborate |
Description: | 9-Mesityl-10-methylacridinium Tetrafluoroborate can be used for the synthesis of γ-butyrolactones, γ-lactams and pyrrolidines. 9-Mesityl-10-methylacridinium Tetrafluoroborate has been reported by Nicewicz et al. to mediate myriad transformations through Photoredox Catalysis. The applications include the anti-Markovnikov hydroamination of alkenes and addition of carboxylic acids to alkenes and the hydrotrifluoromethylation of styrenes using the Langlois reagent S673690. |
Molecular Weight: | 399.23 |
Molecular Formula: | C23H22BF4N |
Canonical SMILES: | [B-](F)(F)(F)F.CC1=CC(=C(C(=C1)C)C2=C3C=CC=CC3=[N+](C4=CC=CC=C42)C)C |
InChI: | InChI=1S/C23H22N.BF4/c1-15-13-16(2)22(17(3)14-15)23-18-9-5-7-11-20(18)24(4)21-12-8-6-10-19(21)232-1(3,4)5/h5-14H,1-4H3/q+1-1 |
InChI Key: | KKMWMXQQOIIJIZ-UHFFFAOYSA-N |
Melting Point: | >80°C (dec.) |
Solubility: | Chloroform (Slightly), Methanol (Slightly) |
Appearance: | Yellow to Dark Yellow Solid |
Storage: | Amber Vial, -20°C Freezer, Under inert atmosphere |
References: | Gesmundo, N. J. et al. Org. Lett. 17, 1316 (2015); Zeller, M. A., et al. Org. Lett. 16, 4810 (2014); Nicewicz et al., J. Am. Chem. Soc., 135 (26), 9588-9591(2013). |
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