6,6'-Dibromo-2,2'-dipyridyl - CAS 49669-22-9
Catalog: |
BB026778 |
Product Name: |
6,6'-Dibromo-2,2'-dipyridyl |
CAS: |
49669-22-9 |
Synonyms: |
2-bromo-6-(6-bromopyridin-2-yl)pyridine |
IUPAC Name: | 2-bromo-6-(6-bromopyridin-2-yl)pyridine |
Description: | 6,6'-Dibromo-2,2'-dipyridyl (CAS# 49669-22-9) is used as a catalyst for the preparation of iodoesters through copper-catalyzed [2,3]-and [1,2]-rearrangements of diazoesters and allylic iodides. |
Molecular Weight: | 313.98 |
Molecular Formula: | C10H6Br2N2 |
Canonical SMILES: | C1=CC(=NC(=C1)Br)C2=NC(=CC=C2)Br |
InChI: | InChI=1S/C10H6Br2N2/c11-9-5-1-3-7(13-9)8-4-2-6-10(12)14-8/h1-6H |
InChI Key: | WZVWSOXTTOJQQQ-UHFFFAOYSA-N |
Boiling Point: | 369.4 °C at 760 mmHg |
Melting Point: | 220-223 °C |
Purity: | 95 % |
Density: | 1.809 g/cm3 |
Appearance: | White to yellow powder or crystals |
MDL: | MFCD00234587 |
LogP: | 3.66860 |
GHS Hazard Statement: | H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation] |
Precautionary Statement: | P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501 |
Signal Word: | Warning |
Publication Number | Title | Priority Date |
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PMID | Publication Date | Title | Journal |
20055470 | 20100215 | Synthesis and characterization of 6,6'-(2,4,6-triisopropylphenyl)-2,2'-bipyridine (tripbipy) and its complexes of the late first row transition metals | Inorganic chemistry |
16292813 | 20051125 | Bridging of bipyridine units by phenylphosphine links: linear and cyclic oligomers and some acid derivatives | The Journal of organic chemistry |
Complexity: | 169 |
Compound Is Canonicalized: | Yes |
Covalently-Bonded Unit Count: | 1 |
Defined Atom Stereocenter Count: | 0 |
Defined Bond Stereocenter Count: | 0 |
Exact Mass: | 313.88772 |
Formal Charge: | 0 |
Heavy Atom Count: | 14 |
Hydrogen Bond Acceptor Count: | 2 |
Hydrogen Bond Donor Count: | 0 |
Isotope Atom Count: | 0 |
Monoisotopic Mass: | 311.88977 |
Rotatable Bond Count: | 1 |
Topological Polar Surface Area: | 25.8 Å2 |
Undefined Atom Stereocenter Count: | 0 |
Undefined Bond Stereocenter Count: | 0 |
XLogP3: | 3.5 |
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