4-Methoxyphenylboronic Acid - CAS 5720-07-0
Catalog: |
BB029610 |
Product Name: |
4-Methoxyphenylboronic Acid |
CAS: |
5720-07-0 |
Synonyms: |
(4-methoxyphenyl)boronic acid; (4-methoxyphenyl)boronic acid |
IUPAC Name: | (4-methoxyphenyl)boronic acid |
Description: | Reagent used for: Suzuki-Miyaura cross-coupling reactions ; Pd-catalyzed direct arylation ; Highly effective synthesis using palladium-catalyzed arylation Suzuki-Miyaura cross-coupling in water ; Palladium-catalyzed stereoselective Heck-type reaction ; Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence ; Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides ; Ruthenium catalyzed direct arylation ; Rh-catalyzed asymmetric conjugate addition ; Ligand-free copper-catalyzed coupling Reagent used in Preparation of; Palladium(II) thiocarboxamide complexes as Suzuki coupling catalyst ; Push-pull arylvinyldiazine chromophores with photophysical properties. |
Molecular Weight: | 151.96 |
Molecular Formula: | C7H9O3B |
Canonical SMILES: | B(C1=CC=C(C=C1)OC)(O)O |
InChI: | InChI=1S/C7H9BO3/c1-11-7-4-2-6(3-5-7)8(9)10/h2-5,9-10H,1H3 |
InChI Key: | VOAAEKKFGLPLLU-UHFFFAOYSA-N |
Boiling Point: | 306.8 °C at 760 mmHg |
Melting Point: | 204-206 °C (lit.) |
Flash Point: | Not applicable |
Purity: | ≥ 95.0 % |
Density: | 1.17 g/cm3 |
MDL: | MFCD00039139 |
LogP: | -0.62500 |
GHS Hazard Statement: | H315 (98.11%): Causes skin irritation [Warning Skin corrosion/irritation] |
Precautionary Statement: | P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501 |
Signal Word: | Warning |
Publication Number | Title | Priority Date |
CN-113480523-A | Preparation method of pimobendan | 20210622 |
CN-113372201-A | Preparation method of biphenol compound and derivatives thereof | 20210610 |
CN-113354810-A | Clustering peptide with side chain containing functionalized biphenyl group and preparation method thereof | 20210607 |
CN-113358616-A | Cell lipid drop fluorescence imaging probe based on dithiophene derivative and application thereof | 20210601 |
CN-113264917-A | Anti-hepatitis B virus compound and preparation method and application thereof | 20210528 |
PMID | Publication Date | Title | Journal |
22614918 | 20120901 | Properties of a model aryl boronic acid and its boroxine | Journal of pharmaceutical sciences |
22374879 | 20120410 | Gold- and silver-catalyzed reactions of propargylic alcohols in the presence of protic additives | Chemistry (Weinheim an der Bergstrasse, Germany) |
21864882 | 20110801 | New synthesis of 6[3-(1-adamantyl)-4-methoxyphenyl]-2-naphthoic acid and evaluation of the influence of adamantyl group on the DNA binding of a naphthoic retinoid | Bioorganic chemistry |
21265538 | 20110304 | A general procedure for the synthesis of enones via gold-catalyzed Meyer-Schuster rearrangement of propargylic alcohols at room temperature | The Journal of organic chemistry |
20977261 | 20101119 | Expanding stereochemical and skeletal diversity using petasis reactions and 1,3-dipolar cycloadditions | Organic letters |
Complexity: | 110 |
Compound Is Canonicalized: | Yes |
Covalently-Bonded Unit Count: | 1 |
Defined Atom Stereocenter Count: | 0 |
Defined Bond Stereocenter Count: | 0 |
Exact Mass: | 152.0644743 |
Formal Charge: | 0 |
Heavy Atom Count: | 11 |
Hydrogen Bond Acceptor Count: | 3 |
Hydrogen Bond Donor Count: | 2 |
Isotope Atom Count: | 0 |
Monoisotopic Mass: | 152.0644743 |
Rotatable Bond Count: | 2 |
Topological Polar Surface Area: | 49.7 Å2 |
Undefined Atom Stereocenter Count: | 0 |
Undefined Bond Stereocenter Count: | 0 |
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