![(3'aS,4'R,5'R,6'aR)-5'-[[(1,1-Dimethylethyl)dimethylsilyl]oxy]hexahydro-5,5-dimethylspiro[1,3-dioxane-2,2'(1'H)-pentalene]-4'-carboxylic Acid Methyl Ester](https://resource.bocsci.com/structure/127708-13-8.gif)
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| IUPAC Name: | methyl (1'R,2'R,3'aR,6'aS)-2'-[tert-butyl(dimethyl)silyl]oxy-5,5-dimethylspiro[1,3-dioxane-2,5'-2,3,3a,4,6,6a-hexahydro-1H-pentalene]-1'-carboxylate |
| Description: | (3'aS,4'R,5'R,6'aR)-5'-[[(1,1-Dimethylethyl)dimethylsilyl]oxy]hexahydro-5,5-dimethylspiro[1,3-dioxane-2,2'(1'H)-pentalene]-4'-carboxylic Acid Methyl Ester is an intermediate in the synthesis of Iloprost (I267300),a synthetic analogue of Prostacyclin (PGI2) used to treat pulmonary arterial hypertension (PAH), scleroderma, raynaud's phenomenon and ischemia. |
| Molecular Weight: | 398.61 |
| Molecular Formula: | C21H38O5Si |
| Canonical SMILES: | CC1(COC2(CC3CC(C(C3C2)C(=O)OC)O[Si](C)(C)C(C)(C)C)OC1)C |
| InChI: | InChI=1S/C21H38O5Si/c1-19(2,3)27(7,8)26-16-9-14-10-21(24-12-20(4,5)13-25-21)11-15(14)17(16)18(22)23-6/h14-17H,9-13H2,1-8H3/t14-,15+,16-,17-/m1/s1 |
| InChI Key: | UMKFYXKVINPPEX-YYIAUSFCSA-N |
| Solubility: | DCM, Ethyl Acetate, Methanol |
| Appearance: | Colourless Oil |
| References: | PCT Int. Appl. (2011), WO 2011003058 A1 20110106.. |
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