2-Dicyclohexylphosphino-2'-methylbiphenyl - CAS 251320-86-2
Catalog: |
BB018757 |
Product Name: |
2-Dicyclohexylphosphino-2'-methylbiphenyl |
CAS: |
251320-86-2 |
Synonyms: |
dicyclohexyl-[2-(2-methylphenyl)phenyl]phosphine; dicyclohexyl-[2-(2-methylphenyl)phenyl]phosphane |
IUPAC Name: | dicyclohexyl-[2-(2-methylphenyl)phenyl]phosphane |
Description: | 2-(Dicyclohexylphosphino)-2'-methyl-biphenyl (CAS# 251320-86-2) can be used as a catalyst precursor to produce higher alcohols from syngas. It can also be used as a delta-lactone derivatives. |
Molecular Weight: | 364.50 |
Molecular Formula: | C25H33P |
Canonical SMILES: | CC1=CC=CC=C1C2=CC=CC=C2P(C3CCCCC3)C4CCCCC4 |
InChI: | InChI=1S/C25H33P/c1-20-12-8-9-17-23(20)24-18-10-11-19-25(24)26(21-13-4-2-5-14-21)22-15-6-3-7-16-22/h8-12,17-19,21-22H,2-7,13-16H2,1H3 |
InChI Key: | GPVWUKXZFDHGMZ-UHFFFAOYSA-N |
Boiling Point: | 499.3 °C at 760 mmHg |
Melting Point: | 105-109 °C |
Flash Point: | Not applicable |
Purity: | 97 % |
MDL: | MFCD03094577 |
LogP: | 7.43460 |
GHS Hazard Statement: | H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation] |
Precautionary Statement: | P261, P264, P271, P272, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P333+P313, P337+P313, P362, P363, P403+P233, P405, and P501 |
Signal Word: | Warning |
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PMID | Publication Date | Title | Journal |
15651780 | 20050121 | Double N-arylation of primary amines: carbazole synthesis from 2,2'-biphenyldiols | The Journal of organic chemistry |
14611232 | 20031119 | Insights into the origin of high activity and stability of catalysts derived from bulky, electron-rich monophosphinobiaryl ligands in the Pd-catalyzed C-N bond formation | Journal of the American Chemical Society |
Complexity: | 388 |
Compound Is Canonicalized: | Yes |
Covalently-Bonded Unit Count: | 1 |
Defined Atom Stereocenter Count: | 0 |
Defined Bond Stereocenter Count: | 0 |
Exact Mass: | 364.231988050 |
Formal Charge: | 0 |
Heavy Atom Count: | 26 |
Hydrogen Bond Acceptor Count: | 0 |
Hydrogen Bond Donor Count: | 0 |
Isotope Atom Count: | 0 |
Monoisotopic Mass: | 364.231988050 |
Rotatable Bond Count: | 4 |
Topological Polar Surface Area: | 0 Å2 |
Undefined Atom Stereocenter Count: | 0 |
Undefined Bond Stereocenter Count: | 0 |
XLogP3: | 7.1 |
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