2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl - CAS 153305-67-0
Catalog: |
BB010880 |
Product Name: |
2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl |
CAS: |
153305-67-0 |
Synonyms: |
[1-[2-bis(4-methylphenyl)phosphino-1-naphthalenyl]-2-naphthalenyl]-bis(4-methylphenyl)phosphine; [1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane |
IUPAC Name: | [1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane |
Description: | 2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl (CAS# 153305-67-0 ) is a useful research chemical. |
Molecular Weight: | 678.78 |
Molecular Formula: | C48H40P2 |
Canonical SMILES: | CC1=CC=C(C=C1)P(C2=CC=C(C=C2)C)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=C(C=C7)C)C8=CC=C(C=C8)C |
InChI: | InChI=1S/C48H40P2/c1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42/h5-32H,1-4H3 |
InChI Key: | IOPQYDKQISFMJI-UHFFFAOYSA-N |
LogP: | 10.41000 |
GHS Hazard Statement: | H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation] |
Precautionary Statement: | P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501 |
Signal Word: | Warning |
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PMID | Publication Date | Title | Journal |
21038042 | 20101214 | Highly enantioselective Cu(I)-Tol-BINAP-catalyzed asymmetric conjugate addition of Grignard reagents to α,β-unsaturated esters | Chemical communications (Cambridge, England) |
20845501 | 20101101 | Probing the stereo-electronic properties of cationic rhodium complexes bearing chiral diphosphine ligands by 103Rh NMR | Magnetic resonance in chemistry : MRC |
20126558 | 20091009 | Iridium-catalyzed asymmetric ring-opening reactions of oxabicyclic alkenes with secondary amine nucleophiles | Beilstein journal of organic chemistry |
19093803 | 20090115 | Stable preformed chiral palladium catalysts for the one-pot asymmetric reductive amination of ketones | Organic letters |
18229932 | 20080306 | A highly catalytic asymmetric conjugate addition: synthesis of the C14-C20 fragment of antibiotic TMC-151A, siphonarienal and siphonarienone | Organic letters |
Complexity: | 897 |
Compound Is Canonicalized: | Yes |
Covalently-Bonded Unit Count: | 1 |
Defined Atom Stereocenter Count: | 0 |
Defined Bond Stereocenter Count: | 0 |
Exact Mass: | 678.26052527 |
Formal Charge: | 0 |
Heavy Atom Count: | 50 |
Hydrogen Bond Acceptor Count: | 0 |
Hydrogen Bond Donor Count: | 0 |
Isotope Atom Count: | 0 |
Monoisotopic Mass: | 678.26052527 |
Rotatable Bond Count: | 7 |
Topological Polar Surface Area: | 0 Å2 |
Undefined Atom Stereocenter Count: | 0 |
Undefined Bond Stereocenter Count: | 0 |
XLogP3: | 12.9 |
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