1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene - CAS 244187-81-3
Catalog: |
BB018464 |
Product Name: |
1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene |
CAS: |
244187-81-3 |
Synonyms: |
1,3-bis[2,6-di(propan-2-yl)phenyl]-2H-imidazol-1-ium-2-ide; 1,3-bis[2,6-di(propan-2-yl)phenyl]-2H-imidazol-1-ium-2-ide |
IUPAC Name: | 1,3-bis[2,6-di(propan-2-yl)phenyl]-2H-imidazol-1-ium-2-ide |
Description: | 1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene (CAS# 244187-81-3) is a useful research chemical. |
Molecular Weight: | 388.60 |
Molecular Formula: | C27H36N2 |
Canonical SMILES: | CC(C)C1=C(C(=CC=C1)C(C)C)N2C=C[N+](=[C-]2)C3=C(C=CC=C3C(C)C)C(C)C |
InChI: | InChI=1S/C27H36N2/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8/h9-16,18-21H,1-8H3 |
InChI Key: | VYCIHDBIKGRENI-UHFFFAOYSA-N |
Boiling Point: | 464.8 °C at 760 mmHg |
Appearance: | Beige solid |
MDL: | MFCD07781991 |
LogP: | 7.81790 |
GHS Hazard Statement: | H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation] |
Precautionary Statement: | P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501 |
Signal Word: | Warning |
Publication Number | Title | Priority Date |
US-2011269917-A1 | Cyclic carbonyl compounds with pendant carbonate groups, preparations thereof, and polymers therefrom | 20100430 |
US-2011243848-A1 | Star polymers, methods of preparation thereof, and uses thereof | 20100330 |
US-2011207902-A1 | Metal-ligand complexes and catalysts | 20100219 |
US-2011201840-A1 | Terminal 1,1-disubstituted alkenes, method of making and using thereof | 20100216 |
US-2011182996-A1 | Surface modified nanoparticles, methods of their preparation, and uses thereof for gene and drug delivery | 20100128 |
PMID | Publication Date | Title | Journal |
22986309 | 20121107 | Reaction of o-carboranes with sterically demanding N-heterocyclic carbene: synthesis and structural characterization of 1 : 1 adducts | Dalton transactions (Cambridge, England : 2003) |
22936368 | 20121028 | Synthesis and catalytic application of palladium imidazol(in)ium-2-dithiocarboxylate complexes | Dalton transactions (Cambridge, England : 2003) |
22786582 | 20120825 | Donor-acceptor stabilized silaformyl chloride | Chemical communications (Cambridge, England) |
22812372 | 20120806 | Arylgold(I) complexes from base-assisted transmetalation: structures, NMR properties, and density-functional theory calculations | Inorganic chemistry |
22180867 | 20120714 | Generation of [(IPr)Pd(PR2Cl)] complexes via P-Cl reductive elimination | Dalton transactions (Cambridge, England : 2003) |
Complexity: | 503 |
Compound Is Canonicalized: | Yes |
Covalently-Bonded Unit Count: | 1 |
Defined Atom Stereocenter Count: | 0 |
Defined Bond Stereocenter Count: | 0 |
Exact Mass: | 388.287849157 |
Formal Charge: | 0 |
Heavy Atom Count: | 29 |
Hydrogen Bond Acceptor Count: | 1 |
Hydrogen Bond Donor Count: | 0 |
Isotope Atom Count: | 0 |
Monoisotopic Mass: | 388.287849157 |
Rotatable Bond Count: | 6 |
Topological Polar Surface Area: | 6.2 Å2 |
Undefined Atom Stereocenter Count: | 0 |
Undefined Bond Stereocenter Count: | 0 |
XLogP3: | 8 |
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