[1,2-Bis(diphenylphosphino)ethane]dichloronickel(II) - CAS 14647-23-5

Catalog: BB043032
Product Name: [1,2-Bis(diphenylphosphino)ethane]dichloronickel(II)
CAS: 14647-23-5
Synonyms: 1,2-Ethylenebis(diphenylphosphine)nickel dichloride; Nickel 1,2-Bis(diphenylphosphino)ethane dichloride; [1,2-Bis(diphenylphosphino)ethane]nickel(II) chloride; dppeNiCl2; Nickel(2+) ion [2-(diphenylphosphanyl)ethyl]diphenylphosphane dichloride; Dichloro[1,2-bis(diphenylphosphino)ethane]nickel(II)
[1,2-Bis(diphenylphosphino)ethane]dichloronickel(II)

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Computed Properties
IUPAC Name:2-diphenylphosphanylethyl(diphenyl)phosphane;nickel(2+);dichloride
Description:Reactant involved in: Kumada catalyst-transfer polycondensation; Oxidation of carboranyl phosphine ligands; Synthesis of nickel-iron dithiolato hydrides; Ullmann reactions - homocoupling reactionsCo-catalyst for hydroformylation of alcohols for the synthesis of quaternary carbon centersCatalyst for Wacker-type intramolecular aerobic oxidative amination of alkenes.
Molecular Weight:528.02
Molecular Formula:C26H24Cl2NiP2
Canonical SMILES:C1=CC=C(C=C1)P(CCP(C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.[Cl-].[Cl-].[Ni+2]
InChI:InChI=1S/C26H24P2.2ClH.Ni/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2
InChI Key:XXECWTBMGGXMKP-UHFFFAOYSA-L
Melting Point:263-265 °C
Purity:> 96.0 % (T)
Appearance:Orange to amber to dark red powder to crystal
Storage:Refrigerator

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