IUPAC Name: | 1,1,1-trifluoro-N-[13-oxo-10,16-bis[2,4,6-tri(propan-2-yl)phenyl]-12,14-dioxa-13λ5-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-yl]methanesulfonamide |
Description: | As a strong chiral Brønsted acid, 1,1,1-Trifluoro-N-[(11bR)-4-oxido-2,6-bis[2,4,6-trisisopropylphenyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl]methanesulfonamide is a chiral N-triflyl phosphoramides organocatalysts for enantioselective synthesis. |
Molecular Weight: | 884.04 |
Molecular Formula: | C51H57F3NO5PS |
Canonical SMILES: | CC(C)C1=CC(=C(C(=C1)C(C)C)C2=CC3=CC=CC=C3C4=C2OP(=O)(OC5=C4C6=CC=CC=C6C=C5C7=C(C=C(C=C7C(C)C)C(C)C)C(C)C)NS(=O)(=O)C(F)(F)F)C(C)C |
InChI: | InChI=1S/C51H57F3NO5PS/c1-27(2)35-23-39(29(5)6)45(40(24-35)30(7)8)43-21-33-17-13-15-19-37(33)47-48-38-20-16-14-18-34(38)22-44(46-41(31(9)10)25-36(28(3)4)26-42(46)32(11)12)50(48)60-61(56,59-49(43)47)55-62(57,58)51(52,53)54/h13-32H,1-12H3,(H,55,56) |
InChI Key: | GBBDKGIJXWZDOQ-UHFFFAOYSA-N |
Boiling Point: | 835.3±75.0 ℃ / 760 mmHg |
Density: | 1.26±0.1 g/mL |
Storage: | Inert atmosphere. Keep cold. |
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Phosphorus Compounds
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Sulfur Compounds
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