1,1'-[(1,1-Dimethylethyl)[[(1R,2E,4E)-5-iodo-1-[3-(trimethylsilyl)-2-propyn-1-yl]-2,4-pentadien-1-yl]oxy]silylene]bis-benzene - CAS 1220354-19-7

Catalog: BB067273
Product Name: 1,1'-[(1,1-Dimethylethyl)[[(1R,2E,4E)-5-iodo-1-[3-(trimethylsilyl)-2-propyn-1-yl]-2,4-pentadien-1-yl]oxy]silylene]bis-benzene
CAS: 1220354-19-7
Synonyms: tert-butyl-[(4R,5E,7E)-8-iodo-1-trimethylsilylocta-5,7-dien-1-yn-4-yl]oxy-diphenylsilane; 1,1'-[(1,1-Dimethylethyl)[[(1R,2E,4E)-5-iodo-1-[3-(trimethylsilyl)-2-propyn-1-yl]-2,4-pentadien-1-yl; 1,1'-[(1,1-Dimethylethyl)[[(1R,2E,4E)-5-iodo-1-[3-(trimethylsilyl)-2-propyn-1-yl]-2,4-pentadien-1-yl]oxy]silylene]bis-benzene
1,1'-[(1,1-Dimethylethyl)[[(1R,2E,4E)-5-iodo-1-[3-(trimethylsilyl)-2-propyn-1-yl]-2,4-pentadien-1-yl]oxy]silylene]bis-benzene
IUPAC Name:tert-butyl-[(4R,5E,7E)-8-iodo-1-trimethylsilylocta-5,7-dien-1-yn-4-yl]oxy-diphenylsilane
Description:1,1'-[(1,1-Dimethylethyl)[[(1R,2E,4E)-5-iodo-1-[3-(trimethylsilyl)-2-propyn-1-yl]-2,4-pentadien-1-yl]oxy]silylene]bis-benzene is an intermediate in the synthesis of Resolvin E1 (R144690), an omega-3 polyunsaturated fatty acid derivative that exhibits potent anti-inflammatory, pro-resolution, and anti-nociceptive effects.
Molecular Weight:558.64
Molecular Formula:C27H35IOSi2
Canonical SMILES:CC(C)(C)[Si](C1=CC=CC=C1)(C2=CC=CC=C2)OC(CC#C[Si](C)(C)C)C=CC=CI
InChI:InChI=1S/C27H35IOSi2/c1-27(2,3)31(25-18-9-7-10-19-25,26-20-11-8-12-21-26)29-24(16-13-14-22-28)17-15-23-30(4,5)6/h7-14,16,18-22,24H,17H2,1-6H3/b16-13+,22-14+/t24-/m0/s1
InChI Key:MILCGFKIDSPDKP-OKYYOCSBSA-N
Solubility:Chloroform, DCM, DMSO, Ethyl Acetate, Methanol,
Appearance:Yellow Oil
Storage:-20°C Freezer
References:Allard, M., et al. Tetrahedron. Lett., 52, 2623 (2011); Allard, M., et al. Tetrahedron. Lett., 52, 6512 (2011).

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